A binuclear vanadium oxyfluoride: di-μ-oxido-bis[(2,2′-bipyridyl)fluoridooxidovanadium(V)]
نویسندگان
چکیده
The title compound, [V(2)F(2)O(4)(C(10)H(8)N)(2)], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The coordination geometries of the symmetry-equivalent V(V) atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.
منابع مشابه
A binuclear vanadium oxyfluoride: di-μ-oxido-bis[fluoridooxido(1,10-phenanthroline)vanadium(V)]
The title compound, [V(2)F(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent V(V) atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is ...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010